Using one spin-transition to trigger another in solid solutions of two different spin-crossover complexes.

نویسنده

  • Malcolm A Halcrow
چکیده

Phase-pure solid solutions of [Co(terpy)(2)][BF(4)](2) and [M(bpp)(2)][BF(4)](2) (M = Fe or Ru, bpp = 2,6-dipyrazol-1-ylpyridine) have been prepared. The spin-state of the [Co(terpy)(2)](2+) dopant is modulated by the spin-state of the [Fe(bpp)(2)](2+) centres in the iron-containing materials.

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عنوان ژورنال:
  • Chemical communications

دوره 46 26  شماره 

صفحات  -

تاریخ انتشار 2010